Confining clay layers typically protect groundwater aquifers against downward intrusion of contaminants.
In the context of groundwater arsenic in Bangladesh, we challenge this notion here by showing that organic carbon drawn from a clay layer into a low-arsenic pre-Holocene (>12 kyr-old) aquifer promotes the reductive dissolution of iron oxides and the release of arsenic. The finding explains a steady rise in arsenic concentrations in a pre-Holocene aquifer below such a clay layer and the repeated failure of a structurally sound community well. Tritium measurements indicate that groundwater from the affected depth interval (40–50 m) was recharged >60 years ago. Deeper (55–65 m) groundwater in the same pre-Holocene aquifer was recharged only 10–50 years ago but is still low in arsenic. Proximity to a confining clay layer that expels organic carbon as an indirect response to groundwater pumping, rather than directly accelerated recharge, caused arsenic contamination of this pre-Holocene aquifer.
- Geosyntec Authors: Ivan Mihajlov
- All Authors: Ivan Mihajlov, Geosyntec Consultants; Rajib Mozumder, Ben Bostick, Martin Stute, Peter Schlosser, Lex van Geen, Columbia University
- Title: Nature Communications, 11, article number 2244
- Event or Publication: Publication
- Practice Areas: Groundwater Assessment and Remediation
- Citation: Ivan Mihajlov, Ph.D. (California) coauthored a paper entitled "Arsenic contamination of Bangladesh aquifers exacerbated by clay layers" that was published in Nature Communications, 11, article number 2244 on May 7, 2020.
- Date: May 7, 2020
- Publication Type: Journal Article